Chemiluminescence of Imino-1,2-dioxetan Formed from Ketenimine and Singlet Oxygen

DOI: 10.1039/c39800000898

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 898 - 900 (1980)

Update date:2022-08-16

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Authors:

Ito, Yoshikatsu

Yokoya, Hiroaki

Kyono, Kazuaki

Yamamura, Soichiro

Yamada, Yutaka

Matsuura, Teruo

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Article abstract of DOI:10.1039/c39800000898

The chemiluminescent properties of several imino-1,2-dioxetans prepared by the photosensitized oxygenation of ketenimines at -78 degC, indicate that the energy level of the transition state for their decomposition to the corresponding ketones and isocyanates is low and that the decomposition proceeds via a biradical mechanism.

Full text of DOI:10.1039/c39800000898

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