Journal of the Chemical Society. Chemical communications p. 898 - 900 (1980)
Update date:2022-08-16
Topics:
Ito, Yoshikatsu
Yokoya, Hiroaki
Kyono, Kazuaki
Yamamura, Soichiro
Yamada, Yutaka
Matsuura, Teruo
The chemiluminescent properties of several imino-1,2-dioxetans prepared by the photosensitized oxygenation of ketenimines at -78 degC, indicate that the energy level of the transition state for their decomposition to the corresponding ketones and isocyanates is low and that the decomposition proceeds via a biradical mechanism.
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Doi:10.1002/cssc.201701127
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