CHEMIE POLYFUNKTIONELLER MOLEKUELE LXXXVII. SYNTHESE UND REAKTIONSVERHALTEN VON 4-METHYL-1,2,6-TRISTIBA-TRICYCLO2,6>HEPTAN (Sb3-NORTRICYCLAN) GEGENUEBER CHROM-, MOLYBDAEN- UND WOLFRAMHEXACARBONYL

DOI: 10.1016/0022-328X(85)87294-6

Source and publish data:

Journal of Organometallic Chemistry p. 307 - 320 (1985)

Update date:2022-08-10

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Authors:

Ellermann, Jochen

Veit, Adolf

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Article abstract of DOI:10.1016/0022-328X(85)87294-6

The reaction of CH3C(CH2Cl)3 and NaSb(C6H5)2 in liquid ammonia leads to Sb2(C6H5)4 (I).Using CH3C(CH2Br)3 instead of CH3C(CH2Cl)3 results in the formation of I and CH3C3 (II).Treatment of II with gaseous HCl in dry CH2Cl2 yields CH3C(CH2SbCl

Full text of DOI:10.1016/0022-328X(85)87294-6

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