Trapping of a reactive tetraruthenium imido cluster with diphenylacetylene

DOI: 10.1021/om00136a036

Source and publish data:

Organometallics p. 1049 - 1051 (1986)

Update date:2022-08-11

Topics:

Authors:

Blohm, Margaret L.

Gladfelter, Wayne L.

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Article abstract of DOI:10.1021/om00136a036

Diphenylacetylene traps the intermediate imido cluster formed during the protonation of [Ru₄N-(CO)₁₂]^-. Structural characterization of the new cluster Ru₄(NH)(PhCCPh)(CO)₁₁ revealed the first example of a tetrabridging imido ligand.

Full text of DOI:10.1021/om00136a036

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