Journal of the Chemical Society, Dalton Transactions p. 2675 - 2680 (1986)
Update date:2022-08-17
Topics:
Bazsa, Gyoergy
Fabian, Istvan
The kinetics of the molybdenium(VI)- and vanadium(V)-catalysed bromate-iodide-ascorbic acid clock reaction has been studied by means of spectrophotometry and pH-metric measurements.Two different types of catalysis were detected in this clock raction.It was shown that MoVI catalyses the component process bromate + iodide of the clock system, while Vv catalyses the direct reaction between bromate and ascorbic acid .The rate equation r = K2
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