RESOLUTION OF ENANTIOMERS BY HPLC ON CELLULOSE TRANS- AND CIS-TRIS(4-PHENYLAZOPHENYLCARBAMATE)

DOI: 10.1246/cl.1986.983

Source and publish data:

Chemistry Letters p. 983 - 986 (1986)

Update date:2022-08-17

Topics:

Authors:

Okamoto, Yoshio

Sakamoto, Hideaki

Hatada, Koichi

Irie, Masahiro

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Article abstract of DOI:10.1246/cl.1986.983

Cellulose tris(4-phenylazophenylcarbamate) ( CPAPC ) having azobenzene pendant groups was adsorbed on silica gel to use as a chiral stationary phase for HPLC.Pure trans-CPAPC resolved many racemic compounds, whereas 70 percent cis-CPAPC showed very poor resolving power.

Full text of DOI:10.1246/cl.1986.983

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