Tetrahedron Letters p. 6081 - 6084 (1990)
Update date:2022-08-10
Topics:
Vona, M. L. Di
Floris, B.
Luchetti, L.
Rosnati, V.
A parallel study of the Clemmensen reaction of benzophenone, 1, benzhydryl chloride, 2, and dichlorodiphenylmethane, 3, suggests new hypotheses about the mechanism of this reduction of diarylketones.Two main pathways have been recognized, both involving ionic and non-ionic reactions.The devised mechanisms provide a tool for interpreting literature data not understood hitherto, concerning Clemmensen-type as well as other zinc-promoted reactions.
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