Journal of Physical Chemistry p. 3233 - 3239 (1982)
Update date:2022-08-16
Topics:
Delcourt, M. O.
Rossi, M. J.
Irradiation at 249 nm of CH3CN solutions of several unsaturated hydrocarbons leads to photoionization resulting in radical cations.Their identity was established by comparison with the products of the ionic photodissociation at 350 nm of exciplexes using chloranil as the electron acceptor.A monophotonic excitation mechanism is suggested, and visible absorption spectra (400-840 nm) of the radical cations and their dimers and their kinetics of disappearance are reported.
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