Tetrahedron Letters p. 2677 - 2680 (1999)
Update date:2022-08-11
Topics:
Byers, Jeffrey H.
Campbell, John E.
Knapp, Faith H.
Thissell, Jameson G.
New methodology for radical aromatic substitution has been developed involving the addition of electron-deficient radicals to unprotected pyrroles and indole. This non-oxidative process is presumed to be occurring via atom- transfer addition of suitable organoiodides and bromides with subsequent non- radical elimination of HI or HBr, respectively. The process also occurs under stannane-free conditions.
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