Journal of the Chemical Society - Faraday Transactions p. 1283 - 1285 (1996)
Update date:2022-08-31
Topics:
Pearson, Jonathan
Orr-Ewing, Andrew J.
Ashfold, Michael N. R.
Dixon, Richard N.
Cavity ring-down spectroscopy of HNO in the range 17 540-17 590 cm-1 reveals that lifetime broadening contributes to the linewidths of the A 1A″-X 1A′ (110)-(000) K′ = 4-K″ = 3 subband rotational transitions. The deconvoluted predissociation-induced widths for the rotational levels of the upper state depend on the value of J′, with the deduced life-times decreasing from 310 ± 160 to 40 ± 6 ps for J′ = 4-16.
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