REDUCTIVE THF-SPALTUNG DURCH LITHIUMSALZE VOLUMINOESER SILAETHANE; INTRAMOLECULARE CYCLISIERUNG CH- UND NH-FUNKTIONELLER VERBINDUNGEN

Article abstract of DOI:10.1016/0022-328X(85)80180-7

The thermal LiHal elimination of CH-SiHal- and NH-SiHal-functional compounds provides a simple synthetic route to four-membered Si-C and Si-N rings.In attempts to inhibit dimerisation sterically, bulky silylmethyl and silylamino substituents were introduc