Journal of Organic Chemistry p. 3919 - 3926 (2019)
Update date:2022-08-10
Topics:
Zhang, Zhiguo
Wang, Songnan
Zhang, Yong
Zhang, Guisheng
Sulfonyl azides have been widely used as sulfonamido, diazo, and azido donors, as well as all-nitrogen 1,3-dipoles donors in synthetic chemistry. Here, the sulfonyl azides were used as efficient sulfonyl donors, which is very unusual. Trifluoromethanesulfonic acid-induced formation of the sulfonyl cation reactive species from sulfonyl azides was developed and used for the first time to couple various inactivated arenes to prepare sulfones at ambient temperature.
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