Silver(I)-catalyzed denitrative trifluoromethylation of β-nitrostyrenes with CF3SO2Na

DOI: 10.1016/j.tetlet.2016.09.016

Source and publish data:

Tetrahedron Letters p. 4705 - 4708 (2016)

Update date:2022-08-11

Topics:

Authors:

Huang, Ping

Li, Yaming

Fu, Xinmei

Zhang, Rong

Jin, Kun

Wang, Wenxin

Duan, Chunying

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Article abstract of DOI:10.1016/j.tetlet.2016.09.016

A novel and convenient approach to the synthesis of substituted β-trifluoromethyl styrenes via a silver(I)-catalyzed denitrative trifluoromethylation with CF₃SO₂Na under relatively mild conditions has been developed. This protocol delivered excellent stereoselectivity and showed wide substrate tolerance.

Full text of DOI:10.1016/j.tetlet.2016.09.016

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