Synthesis p. 534 - 535 (1988)
Update date:2022-08-16
Topics:
Rodriguez, J.
Waegell, B.
α,β-Unsaturated aldehydes react with monoalkyl malonates in pyridine with a catalytic amount of dimethylaminopyridine (DMAP) in a regio- and stereoselective process to yield almost exclusively 2,4-pentadienoic esters with essentially (and in many cases exclusively) the 2E-stereochemistry.
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