Directed regioselective Ni-catalyzed alkylation and hydride addition of allylic ethers. A remarkable turnover in regioselectivity

DOI: 10.1016/0040-4039(96)00660-0

Source and publish data:

Tetrahedron Letters p. 3613 - 3616 (1996)

Update date:2022-08-16

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Authors:

Morken, James P.

Didiuk, Mary T.

Hoveyda, Amir H.

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Article abstract of DOI:10.1016/0040-4039(96)00660-0

Various allylic ethers are reduced efficiently in the presence of Ni(PPh₃)₂Cl₂ (5 mol%) and EtMgCl (5 equiv) with excellent regioselectivity (>99:1). The sense of regiochemical control in these reactions is opposite to tha

Full text of DOI:10.1016/0040-4039(96)00660-0

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