Carbohydrate Research p. 63 - 70 (1989)
Update date:2022-08-29
Topics:
Descotes, Gerard
Mentech, Julio
Roques, Nathalie
A divergent synthesis of 6-deoxy (5), 4-deoxy (9), and 3-deoxy (15) derivatives of sucrose, after acetalation of sucrose with 2,2-dimethoxypropane, is detailed.Thus, 5 was prepared by hydrogenolysis of 6-S-(2-pyridyl)-6-thiosucrose, whereas 9 and 15 were obtained by radical reduction of the corresponding thiocarbonyl derivatives.
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