Journal of the American Chemical Society p. 300 - 308 (1989)
Update date:2022-08-02
Topics:
Overman
Robichaud
(+)-Geissoschizine (1) was prepared in an efficient and stereocontrolled fashion in 11 steps and 7.5% overall yield from (S)-tryptophanamide (20). Key steps are the stereoselective 1,4-addition of cuprate 13a to tetracyclic intermediate 8, which establish
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