Journal of the Chemical Society. Chemical communications p. 855 - 856 (1981)
Update date:2022-08-11
Topics:
Nakagawa, Masako
Kato, Shiro
Nakano, Kumiko
Hino, Tohru
Exclusive conversion of the tricyclic hydroperoxide (1) into N'-formylkynurenine (2) has been found to occur in Na2CO3-AcOH (pH 7) and the methylene blue-sensitized photo-oxygenation of tryptophan in the same system has given N'-formylkynurenine as the sole product, in contrast with the reaction in water, which gave compound (1).
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