ZIRCONIUM ENOLATES AS A NEW ERYTHRO-SELECTIVE ALDOL CONDENSATION REAGENT

DOI: 10.1016/0040-4039(80)80086-4

Source and publish data:

Tetrahedron Letters p. 4607 - 4610 (1980)

Update date:2022-08-11

Topics:

Authors:

Yamamoto, Yoshinori

Maruyama, Kazuhiro

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Article abstract of DOI:10.1016/0040-4039(80)80086-4

Zirconium enolates, prepared from lithium enolates, ans bis(cyclopentadienyl)zirconium dichloride, undergo a facile aldol condensation with aldehydes to give predominantly the erythro product regardless of the geometry of the starting enolates.

Full text of DOI:10.1016/0040-4039(80)80086-4

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