Journal of Organic Chemistry p. 2609 - 2612 (1998)
Update date:2022-08-16
Topics:
Xiao, Wen-Jing
Vasapollo, Giuseppe
Alper, Howard
A series of mono- and di-substituted allenes underwent direct thiocarbonylation with thiols and carbon monoxide to form the corresponding β,γ-unsaturated thioesters in 73-94% yields. This reaction requires catalytic quantities of Pd(OAc)2 (3 mo
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