Journal of Organic Chemistry p. 5123 - 5125 (1989)
Update date:2022-08-10
Topics:
Abad, A.
Agullo, C.
Arno, M.
Cunat, A. C.
Zaragoza, R. J.
An efficient transformation of the diene 1, obtained in three steps from commercial colophony or abietic acid, into (+)-ambreinolide (10) was developed.The sequence was carried out in 47-57percent overall yield and involves as the key step the rearrangement of the epoxy lactone 6 to produce the intermediate dial 7.
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