Journal of Organic Chemistry p. 2359 - 2361 (1980)
Update date:2022-08-11
Topics:
Akiyama, Fumitaka
Miyazaki, Hiroshi
Kaneda, Kiyotomi
Teranishi, Shiichiro
Fujiwara, Yuzo
et al.
Arylamines (ArNH2) have been found to function as arylating agents by way of C-N bond cleavage to give aryl-substituted olefins when treated with palladium salts and acetic acid.The reactivity of various amines and olefins has been investigated.Hydrazines such as phenylhydrazine and methylhydrazine are also able to act as arylating and alkylating agents, respectively.The addition of tert-butyl nitrite greatly increases the yields.
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