REDUCTION OF Z-2-CHLOROSTILBENE WITH LITHIUM ALUMINUM HYDRIDE: EVIDENCE FOR AN ELECTRON TRANSFER RADICAL MECHANISM

DOI: 10.1016/0040-4039(80)88113-5

Source and publish data:

Tetrahedron Letters p. 4753 - 4756 (1980)

Update date:2022-08-17

Topics:

Authors:

Singh, P. R.

Nigam, Alok

Khurana, J. M.

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Article abstract of DOI:10.1016/0040-4039(80)88113-5

Z-2-Chlorostilbene undergoes uncatalyzed LiAlH4 reduction giving phenanthrene and Z-stilbene.An electron transfer radical mechanism is proposed.LiAlH4 induced isomerization of Z-stilbene produces E-stilbene.

Full text of DOI:10.1016/0040-4039(80)88113-5

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