REDUCTION OF Z-2-CHLOROSTILBENE WITH LITHIUM ALUMINUM HYDRIDE: EVIDENCE FOR AN ELECTRON TRANSFER RADICAL MECHANISM

DOI: 10.1016/0040-4039(80)88113-5

Source and publish data:

Tetrahedron Letters p. 4753 - 4756 (1980)

Update date:2022-08-17

Topics:

Authors:

Singh, P. R.

Nigam, Alok

Khurana, J. M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(80)88113-5

Z-2-Chlorostilbene undergoes uncatalyzed LiAlH4 reduction giving phenanthrene and Z-stilbene.An electron transfer radical mechanism is proposed.LiAlH4 induced isomerization of Z-stilbene produces E-stilbene.

Full text of DOI:10.1016/0040-4039(80)88113-5

Products guided by the article

Product name:trans-Stilbene

Cas No:103-30-0

R&D Labs maybe for 103-30-0

Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.

Contact:+86-576-87501888 / 87501988

Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai
ChangZhou XiaQing Chemical Co., Ltd.

Contact:+86-519-88721665

Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
Amadis Chemical Co., Ltd.

website:http://www.amadischem.com

Contact:86-571-89925085

Address:Watts Cosine.No.166.Xiangmao Road.

Relevant to this article

Concerted mechanisms of the reactions of phenyl and 4-nitrophenyl chlorothionoformates with substituted phenoxide ions

Doi:10.1021/jo980284u
(1998)
Thiol-dependent DNA cleavage by 3H-1,2-benzodithiol-3-one 1,1-dioxide

Doi:10.1016/S0960-894X(00)00125-6
(2000)
Integrating amino groups within conjugated microporous polymers by versatile thiol-yne coupling for light-driven hydrogen evolution

Doi:10.1039/c9ta04018h
(2019)
Preparation of NiO Nanocatalyst Supported on MWCNTs and Its Application in Reduction of Nitrobenzene to Aniline in Liquid Phase

Doi:10.1080/15533174.2013.862646
(2016)
Direct N.m.r. Observation of Cell-free Conversion of (L-α-Amino-δ-adipyl)-L-cysteinyl-D-valine into Isopenicillin N

Doi:10.1039/c39800001271
(1980)
Alkaline degradation of monosaccharides V: Kinetics of the alkaline isomerization and degradation of monosaccharides

Doi:10.1002/recl.19871060201
(1987)

Article Doi