Tetrahedron Letters p. 949 - 952 (1997)
Update date:2022-08-30
Topics:
Motschiedler, Krista R.
Toscano, John P.
Garcia-Garibay, Miguel A.
Inter- and intramolecular triplet sensitization of two 1,2-diaryldiazoethanes in methanol gives rise to stilbenes 3 and ether 5 intramolecular 1,2-H shifts and intermolecular reaction with methanol, respectively. The sensitized results were compared with those obtained from direct photolysis to determine the relative importance of excited state reactivity of the diazo precursors.
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