Journal of Organometallic Chemistry p. 141 - 145 (1999)
Update date:2022-08-11
Topics:
Herrmann, Wolfgang A.
Boehm, Volker P.W.
Phospha-palladacycles are among the most powerful palladium catalyst systems for the Heck reaction. We have shown the use of non-aqueous ionic liquids (NAILs) as an alternative to traditional molecular solvents for this reaction, with the phospha-palladacycle catalysts resulting in easy product separation, possible catalyst recycling and further increases in catalyst productivity. Preliminary results obtained with bromo- and chloro arenes are presented.
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