ALKALI METAL FLUORIDE MEDIATED SILYL-REFORMATSKY REACTION IN SOLID-LIQUID MEDIA; ACTIVATION BY MICROWAVES.

DOI: 10.1016/S0040-4039(00)92038-0

Source and publish data:

Tetrahedron Letters p. 1179 - 1182 (1991)

Update date:2022-08-16

Topics:

Authors:

Latouche, Regine

Texier-Boullet, Francoise

Hamelin, Jack

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Article abstract of DOI:10.1016/S0040-4039(00)92038-0

Condensation of trimethylsilylacetonitrile or ethyltrimethylsilylacetate with benzaldehyde, in the presence of dried alkali metal fluorides in heterogeneous media under microwaves leads readily to β-trimethylsilyloxynitrile or ester according to a Reformatsky type reaction.The later products could be hydrolyzed and dehydrated on the wet inorganic salt to give the corresponding alkenes.

Full text of DOI:10.1016/S0040-4039(00)92038-0

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