THE HYDROGENATION OF STYRENES BY HYDRIDOCOBALT TETRACARBONYL

DOI: 10.1016/S0022-328X(00)86792-3

Source and publish data:

Journal of Organometallic Chemistry p. 271 - 276 (1982)

Update date:2022-08-30

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Authors:

Roth, Jerome A.

Wiseman, Paul

Ruszala, Lois

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Article abstract of DOI:10.1016/S0022-328X(00)86792-3

The rates of hydrogenation of several styrene derivatives by stoichiometric hydridocobalt tetracarbonyl were measured and compared.The relative rates are discussed in terms of conjugative and steric effects on the geminate radical pair mechanism.An improved method for determining HCo(CO)4 concentration is described.

Full text of DOI:10.1016/S0022-328X(00)86792-3

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