Journal of the Chemical Society. Chemical communications p. 1790 - 1792 (1989)
Update date:2022-08-23
Topics:
Akita, Munetaka
Oku, Tomoharu
Moro-oka, Yoshihiko
Thermal reaction of (cp)Fe(CO)2(R), (cp)Fe(CO)2(COR), and (cp)Fe(CO)(PPh3)(COR) (cp = C5H5) with 3 equivalents of trimethyl-stannane or -silane, affords R-CH2OH (or R-CH2OSiMe3) and (cp)Fe(CO)H(MMe3)2 in good yields; the reaction sequence follows initial reduction of transient co-ordinatively unsaturated acyl species to give the aldehyde and successive hydrometallation by the action of Me3M-Fe intermediates.
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