Tetrahedron p. 3665 - 3674 (1995)
Update date:2022-08-17
Topics:
Booth, Susan E.
Benneche, Tore
Undheim, Kjell
A method for α-alkylation of saturated 5-, 6-, 7- and 8-membered aza-heterocycles is described.The auxiliary is an o-iodobenzyl group attached at the nitrogen.A radical introduced in the o-position is transferred to the amine α-position which subsequently leads to an addition reaction with pentan-3-one.
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