Tetrahedron Letters p. 1069 - 1070 (1988)
Update date:2022-08-28
Topics:
Cha, Jin Soon
Yoon, Mal Sook
Kim, Young Shick
Lee, Kwang Woo
A new class of reducing agents, potassium 9-alkyl-9-boratabicyclo<3.3.1>nonanes (K 9-R-9-BBNHs) was examined its stereoselectivity toward cyclic ketones.Among these, K 9-TB-9-BBNH reveals the most favorable stereoselectivity, comparable to that by lithium trisiamylborohydride at 0 deg C.
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