Facile and highly stereoselective allylation of aldehydes using allyltrichlorosilanes in DMF

DOI: 10.1016/S0040-4039(00)79181-7

Source and publish data:

Tetrahedron Letters p. 3453 - 3456 (1993)

Update date:2022-08-11

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Authors:

Kobayashi, Shu

Nishio, Koichi

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Article abstract of DOI:10.1016/S0040-4039(00)79181-7

Allyltrichlorosilanes regioselectively react with aldehydes in N,N-dimethylformamide (DMF) without catalyst to afford the corresponding homoallylic alcohols in high yields. Syn and anti homoallylic alcohols are stereoselectively obtained from (Z)- and (E)

Full text of DOI:10.1016/S0040-4039(00)79181-7

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