Deprotection and direct oxidative deprotection of trimethylsilyl ethers to their corresponding alcohols and carbonyl compounds with tris[trinitratocerium(IV)] paraperiodate, [(NO3)3Ce]3.H2IO6, in an aprotic solvent

Article abstract of DOI:10.1080/00397919608003633

Deprotection of structurally different trimethylsilyl ethers to their corresponding alcohols has been achieved in refluxing benzene in the presence of tris[trinitratocerium(IV)] paraperiodate in a few minutes. This reagent has also been used successfully for the direct oxidation of trimethylsilyl ethers to their corresponding carbonyl compounds. Benzylic double bonds are prone to cleavage reactions with this method.

Full text of DOI:10.1080/00397919608003633

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Deprotection and Direct
Oxidative Deprotection of
Trimethylsilyl Ethers to their
Corresponding Alcohols and
Carbonyl Compounds with
Tris[trinitratocerium(IV)]
Paraperiodate,
[(NO3)3Ce]3.H2IO6, in an
Aprotic Solvent
H. Firouzabadi a & F. Shiriny a
a Chemistry Department , Shiraz University ,
Shiraz, 71454, Iran
Published online: 21 Aug 2006.
To cite this article: H. Firouzabadi & F. Shiriny (1996) Deprotection and
Direct Oxidative Deprotection of Trimethylsilyl Ethers to their Corresponding
Alcohols and Carbonyl Compounds with Tris[trinitratocerium(IV)] Paraperiodate,
[(NO3)3Ce]3.H2IO6, in an Aprotic Solvent, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry,
26:3, 423-432, DOI: 10.1080/00397919608003633
To link to this article: http://dx.doi.org/10.1080/00397919608003633

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