LIGAND-TO-GUEST CONVERSION OF p-TOLUIDINE MOLECULE IN METAL COMPLEX BIS(p-TOLUIDINE)-1,6-DIAMINOHEXANECADMIUM(II) TETRACYANONICKELATE(II) AND FORMATION OF CLATHRATE COMPOUND 1,6-DIAMINOHEXANECADMIUM(II) TETRACYANONICKELATE(II)-p-TOLUIDINE(1/1)

Article abstract of DOI:10.1246/cl.1986.793

Bis(p-toluidine)-1,6-diaminohexanecadmium(II) tetracyanonickelate (II) is thermally converted to a clathrate compound 1,6-diaminohexanecadmium(II) tetracyanonickelate(II))-p-toluidine(1/1) in the intermediate stage of thermal decomposition under ambient atmosphere.The clathrate is prepared in another way by the method similar to those applied to the o- and m-isomer clathrates but using more dilute guest-diluent mixture.