Tetrahedron p. 1747 - 1766 (1996)
Update date:2022-08-17
Topics:
Vasudeva, Pejakala K.
Nagarajan, Madhavarao
By the proper choice of metal counterion it is possible to regioselectively cleave with a variety of nucleophiles, the epoxide ring of benzyl 3, 4-anhydro-β-D-ribopyranoside. The resulting 3-deoxy 3-substituted or 4-deoxy 4-substituted glycosides were obtained in good yields. Factors governing the regiochemistry of ring opening are discussed.
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