The Crystal Structures of 22> and 2 and Their Use as Catalytic Oxidants

DOI: 10.1039/DT9950003131

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3131 - 3138 (1995)

Update date:2022-08-17

Topics:

Authors:

Griffith, William P.

Parkin, Bernadeta C.

White, Andrew J. P.

Williams, David J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950003131

The new trinuclear heteropolyperoxo complexes 2<(RPO3)2> (R = Ph, M = Mo 1 or W 2) have been isolated and the crystal structure of the molybdenum complex is reported.A series of analogous molybdenum complexes (R = Me, Et, n-Bu, or t-Bu; M = Mo) have also been synthesised and characterised.The use of these compounds as catalysts for the epoxidation of alkenes, oxidation of alcohols and of tertiary amines with hydrogen peroxide as cooxidant has been studied, and complex 2 is shown to be particularly effective for such oxidations.The crystal structure of the new tetranuclear isopolyperoxo species 2 3 is also reported and its properties as a catalyst for alkene epoxidation with hydrogen peroxide as cooxidant studied.

Full text of DOI:10.1039/DT9950003131

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Menthone

Cas No:10458-14-7

R&D Labs maybe for 10458-14-7

JIANGXI ZHANGFENG CHEMICAL CO., LTD.

Contact:+86-0799-3413066

Address:Xiyuan village, Xiabu Town, Xiangdong District
Shijiazhuang Sdyano Fine Chemical Co., Ltd

Contact:+86-311-89830448

Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Synasia Inc

Contact:17316303296

Address:240 Amboy Ave
Fusilin chemical science & technology co., ltd.

Contact:532-80698166/86057573, +86-400-669-7885

Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
Hangzhou utanpharma Co., Ltd

Contact:0571-86821378 ,86820258,56836287,56830923,

Address:Block D ,20F, Tianyuan Building,No.508, Wensan RD, 310013,Hangzhou Zhejiang China

Relevant to this article

Radioiodinated phenoxyacetic acid derivatives as potential brain imaging agents. II. Structure-biodistribution relationship

Doi:10.1248/cpb.37.2282
(1989)
Highly Selective Hydrodecarbonylation of Oleic Acid into n-Heptadecane over a Supported Nickel/Zinc Oxide-Alumina Catalyst

Doi:10.1002/cctc.201500418
(2015)
Design and synthesis of 1,2,4-triazolo[1,5-a]pyrimidine derivatives as PDE 4B inhibitors endowed with bronchodilator activity

Doi:10.1002/ardp.201900002
(2019)
Aryl-Substituted boron subphthalocyanines and their application in organic photovoltaics

Doi:10.1071/CH15381
(2015)
Discovery of a series of novel compounds with moderate anti-hepatitis C virus NS3 protease activity in vitro

Doi:10.1016/j.bmc.2015.07.032
(2015)
Hypercoordinate ketone adducts of electrophilic π³-H₂SiRR′ ligands on ruthenium as key intermediates for efficient and robust catalytic hydrosilation

Doi:10.1021/ja509073c
(2014)

Article Doi