Journal of the Chemical Society. Chemical communications p. 2103 - 2104 (1994)
Update date:2022-08-23
Topics:
Yanagisawa, Akira
Yasue, Katsutaka
Yamamoto, Hisashi
Reaction of a variety of 1,2-epoxyalkanes with 2.5 equiv. of bulky metal amide - lithium 2,2,6,6-tetramethylpiperidide - affords the corresponding aldehydes exclusively in high yields; this is the first example of base-promoted isomerization of monosubstituted epoxides to aldehydes.
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