Optical Resolution and Absolute Configuration of Axially Dissymmetric 2,2'-Dihydroxy-6,6'-Dimethylbiphenyl

DOI: 10.1246/bcsj.60.2307

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2307 - 2309 (1987)

Update date:2022-08-17

Topics:

Authors:

Kanoh, Shigeyoshi

Tamura, Nobuyuki

Motoi, Masatoshi

Suda, Hiroshi

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Article abstract of DOI:10.1246/bcsj.60.2307

2,2'-Dihydroxy-6,6'-dimethylbiphenyl (1) was successfully resolved into its optically pure forms by the recrystallization of the diastereomeric salts derived from the hydrogenphosphate of 1 and cinchonidine or quinine.The dextrorotatory 1 was determined to have R-configuration.

Full text of DOI:10.1246/bcsj.60.2307

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