Phytochemistry p. 607 - 611 (2000)
Update date:2022-08-11
Topics:
Johns, Lesley
Belt, Simon
Lewis, C. Anthony
Rowland, Steven
Masse, Guillaume
Robert, Jean-Michel
Koenig, Wilfried A.
The partial configurations of C25 isoprenoid alkenes isolated from the diatom Haslea ostrearia Gaillon (Simonsen) have been established. A combination of NMR spectroscopy studies of the alkenes with chiral shift reagents in conjunction with soluble silver β-diketonate complexes and enantioselective gas chromatography of oxidation products of the alkenes was used. Unexpected differences in highly branched isoprenoid isomer configurations were observed between different laboratory cultures of the alga. (C) 2000 Elsevier Science Ltd.
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(2000)
