PHENYLATION D'ALCOOLS ALLYLIQUES ACYCLIQUES IIa.REGIOSELECTIVITE DU TRANSFERT D'HYDROGENE

DOI: 10.1016/S0040-4039(01)90043-7

Source and publish data:

Tetrahedron Letters p. 1793 - 1796 (1984)

Update date:2022-07-30

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Authors:

Smadja, William

Ville, Guy

Cahiez, Gerard

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Article abstract of DOI:10.1016/S0040-4039(01)90043-7

PdCl2, HNaCO3-catalysed phenylation of deuterium-labelled allylic butenols, a Heck type reaction, proceeds by a highly regioselective 1,2-hydrogen shift via a Wacker type intermediate.No decomplexed enol was formed during this reaction.

Full text of DOI:10.1016/S0040-4039(01)90043-7

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