Asymmetric γ-Selective Pentadienylation of Aldehydes Catalyzed by BINAP·Ag(I) Complex

DOI: 10.1055/s-1997-945

Source and publish data:

Synlett p. 933 - 934 (1997)

Update date:2022-08-17

Topics:

Authors:

Yanagisawa, Akira

Nakatsuka, Yoshinari

Nakashima, Hiroshi

Yamamoto, Hisashi

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Article abstract of DOI:10.1055/s-1997-945

Reaction of aldehydes with (E)-2,4-pentadienyltributyltin or trimethyltin in the presence of a catalytic amount of BINAP-silver(I) complex affords the corresponding γ-pentadienylated optically active alcohols with high enantioselectivities.

Full text of DOI:10.1055/s-1997-945

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