Journal of Organic Chemistry p. 1801 - 1803 (1987)
Update date:2022-08-15
Topics:
O'Connor, Brian
Just, George
Syntheses of (6Z,9Z)-heneicosadiene, a component of the sex attractant secretion of the female arctiid moth (Uthetheisa ornatrix), and of triene 6, a useful precursor for the synthesis of (8S)-HETE, are described using a one-pot four-component (cuprate-acetylene-vinyltriphenylphosphonium bromide-aldehyde) reaction.The use of 1-iodo-1-alkenes as an alternative to Normant's alkenylcuprate methodology is demonstrated.
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(1986)
