Chemical Communications p. 3405 - 3407 (2008)
Update date:2022-08-05
Topics:
Katagiri, Takashi
Tsurugi, Hayato
Satoh, Tetsuya
Miura, Masahiro
Cross-dimerization of various terminal alkynes with different bulky terminal alkynes such as triisopropylsilylacetylene and 1-trimethylsilyloxy-1,1- diphenyl-2-propyne efficiently proceeds in the presence of a rhodium catalyst system to produce the corresponding (E)-enynes with high regio- and stereoselectivity. The Royal Society of Chemistry.
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