Journal of Organic Chemistry p. 8820 - 8823 (2007)
Update date:2022-08-10
Topics:
Tamaso, Ken-Ichi
Hatamoto, Yuji
Obora, Yasushi
Sakaguchi, Satoshi
Ishii, Yasutaka
(Chemical Equation Presented) A new synthetic method of substituted furoates from acrylates and aldehydes was developed by Pd-(OAc)2 combined with molybdovanadophosphoric acid and Lewis acid under atmospheric dioxygen. The reaction was found to proceed through the palladium-catalyzed acetalization of acrylates with methanol followed by the reaction of the resulting acetals with aldehydes.
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