Kinetic influences on enantioselectivity in asymmetric catalytic hydrogenation

DOI: 10.1016/S0022-328X(97)00165-4

Source and publish data:

Journal of Organometallic Chemistry p. 65 - 72 (1997)

Update date:2022-08-11

Topics:

Authors:

Sun, Yongkui

Wang, Jian

LeBlond, Carl

Reamer, Robert A.

Laquidara, Joseph

Sowa Jr., John R.

Blackmond, Donna G.

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Article abstract of DOI:10.1016/S0022-328X(97)00165-4

The influence of reaction conditions on enantioselectivity in the Ru^II-(binap)-catalyzed asymmetric hydrogenation of allylic alcohols is discussed. This work highlights the importance of considering kinetic influences in addition to the stereochemical aspects of the chiral catalytic environment in interpreting catalytic behavior in asymmetric hydrogenation reactions.

Full text of DOI:10.1016/S0022-328X(97)00165-4

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