
Journal of the Chemical Society. Chemical communications p. 1051 - 1053 (1992)
Update date:2022-08-30
Topics:
Battioni, P.
Bartoli, J. F.
Mansuy, D.
Byun, Y. S.
Traylor, T. G.
Reaction of silica, montmorillonite and polystyrene bearing amino functions with several polyhalogenated metalloporphyrins gave an easy one-step access to new supported catalysts, owing to a selective nucleophilic substitution of the para-halogen atoms of the porphyrin meso-aryl groups by the polymer amine function; these catalysts were very active for cyclooctene epoxidation and alkane hydroxylation by PhIO.
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