Manganese(II) based Oxidation of Alkanes: Generation of a High Valent Binuclear Catalyst in situ

DOI: 10.1039/c39940001885

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1885 - 1886 (1994)

Update date:2022-08-11

Topics:

Authors:

Menage, Stephane

Collomb-Dunand-Sauthier, Marie-Noe.

Lambeaux, Claude

Fontecave, Marc

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940001885

The efficiently Mn2+ -catalysed oxidation of saturated hydrocarbons by alkylhydroperoxides or iodosylbenzene in the presence of 2,2'-bipyridine in acetonitrile follows the following pathway: Mn2+ + bipy -> 2+ -> 3+, the latter being identified as the catalytic species; it affords cyclohexanol and cyclohexanone in equal amounts and the remarkable robustness of the active complex, under oxidative conditions, is noted.

Full text of DOI:10.1039/c39940001885

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3-Heptanone

Cas No:106-35-4

R&D Labs maybe for 106-35-4

Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang
Zhuhai Biliantian Bio-Tech Co., Ltd.(expird)

Contact:0756-7716996

Address:Gongyuan Raod,Zhuhai,Guangdong Prov.China.
Shandong Ailitong New Material Co.,Ltd

Contact:+86-536-3226266

Address:zhongjia village, putong town , qingzhou city,Shandong Province,China
Shanghai MissYou Chemical Co.,Ltd.

Contact:86-21-58583907

Address:Room606A,?No.800?Shangcheng?Road,?Pudong?New?Area,?Shanghai,?China

Relevant to this article

Ruthenium trichloride as a new catalyst for selective production of dimethoxymethane from liquid methanol with molecular oxygen as sole oxidant

Doi:10.1016/j.catcom.2015.04.031
(2015)
A novel oxidative reaction of 2-nitro-1-phenylpropane with sodium nitrite. A new approach to prepare 1-oximino-1-phenylacetones

Doi:10.1016/j.tetlet.2003.09.054
(2003)
Photoaddition Reactions of Benzoxazole-2(3H)-thiones to Cycloalkenes and Heteroaromatics

Doi:10.1002/hlca.200390266
(2003)
Doi:10.1021/ac60093a011
(1954)
Structure of 1-tert-butyl-3-hydroxymethyl-3-nitroazetidine and 1-bromoacetyl-3,3-dinitroazetidine, an investigative anticancer agent derived from energetic materials

Doi:10.1007/s10870-013-0421-2
(2013)
Study of Mesomorphism Through a Novel Homologous Series and Its Relation to Molecular Structure

Doi:10.1080/15421406.2014.915630
(2015)

Article Doi