Facile deprotection of trimethylsilyl ethers with modified borohydride agents; 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tetrahydroborate (BAAOTB) versus tetrabutylammonium tetrahydroborate(TBATB)

Article abstract of DOI:10.1080/00397919608003713

Deprotection structurally different trimethylsilyl ethers with the modified borohydride agents BAAOTB and TBATB to their corresponding alcohols in reflexing t-BuOH is described. Both BAAOTB and TBATB are efficient reagents for this purpose. BAAOTB seems to be more selective than TBATB.

Full text of DOI:10.1080/00397919608003713

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Facile Deprotection of
Trimethylsilyl Ethers With
Modified Borohydride
Agents; 1-Benzyl-4-AZA-1-
Azoniabicyclo[2.2.2]Octane
1
Tetrahydroborate (Baaotb)
Versus Tetrabutylammonium
Tetrahydroborate(TBATB)
a
a
H. Firouzabadi & G. R. Afsharifar
a
Chemistry Department , Shiraz University
Shiraz , 71454, Iran
Published online: 21 Aug 2006.
To cite this article: H. Firouzabadi & G. R. Afsharifar (1996) Facile Deprotection
of Trimethylsilyl Ethers With Modified Borohydride Agents; 1-Benzyl-4-
1
AZA-1-Azoniabicyclo[2.2.2]Octane Tetrahydroborate (Baaotb) Versus
Tetrabutylammonium Tetrahydroborate(TBATB), Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry,
26:6, 1065-1073, DOI: 10.1080/00397919608003713
To link to this article: http://dx.doi.org/10.1080/00397919608003713
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