Journal of the Chemical Society. Chemical communications p. 839 - 840 (1993)
Update date:2022-08-30
Topics:
McLellan, Jill F.
McNab, Hamish
Muir, Thomas W.
Flash vacuum pyrolysis of N-(p-chlorophenoxymethyl)azoles (e.g. 2 and 3) gives ring expanded products (e.g. 4 and 8) formed via N-heteroarylmethyl radicals (e.g. 1 and 6); the mechanism of ring expansion generally involves a novel 'walk'-rearrangement of the radical centre.
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