Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 84 - 91 (1980)
Update date:2022-08-17
Topics:
Weeks, Thomas J.
Ladd, Irwin R.
Bolton, Anthony P.
The cracking mechanism of (5-(13)C)-n-nonane has been studied over quartz wool, silica-alumina and a type Y zeolite.The products observed at a reaction temperature of 510 deg C over quartz wool agree reasonably well with the currently accepted mechanism of free radical cracking.Reaction with silica-alumina at 500 deg C and zeolite at 230 deg C results in a (13)C labelled product distribution which agrees with neither a thermal cracking mechanism nor the currently accepted mechanism of β-scission of carbonium ion intermediates.Rather, the data suggest that the product distribution is a result of the temperature-dependent random description and cracking of a complex polymeric precursor.
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