
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1511 - 1522 (1989)
Update date:2022-08-11
Topics:
Sarkany, Antal
Transformation of n-pentane, 2-methylbutane and 2,2-dimethylbutane has been investigated as a function of the H2/hydrocarbon ratio over a 10 wtpercent Ir/Al2O3 catalyst of 14 percent dispersion.The selectivity of isomer formation has been observed to decrease with the increase of the H2/hydrocarbon ratio and follow the sequence n-pentane > 2-methylbutane >> 2,2-dimethylbutane.The effect of the experimental conditions on the product selectivity has been interpreted considering the actual surface state of the working catalyst.
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