On the Biosynthesis of Ethylene. Determination of the Stereochemical Course using Modified Substrates

DOI: 10.1039/c39850001496

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1496 - 1498 (1985)

Update date:2022-08-30

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Authors:

Baldwin, Jack E.

Adlington, Robert M.

Lajoie, Gilles A.

Rawlings, Bernard J.

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Article abstract of DOI:10.1039/c39850001496

The conversion of a series of specifically 2-alkylated-3-deuteriated-1-aminocyclopropanecarboxylates by apple tissue into mixtures of cis- and trans-1-deuterioalk-1-enes is reported; the results are in accord with a stepwise enzymatic mechanism of cyclopropane ring opening in which stereochemical equilibration is faster than the subsequent bond breaking process.

Full text of DOI:10.1039/c39850001496

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